Title of article :
1,4-Addition of aryl boronic acids to α,β-unsaturated ketones catalyzed by a CCC–NHC pincer rhodium complex
Author/Authors :
Reilly، نويسنده , , Sean W. and Box، نويسنده , , Hannah K. and Kuchenbeiser، نويسنده , , Glenn R. and Rubio، نويسنده , , Ramel J. and Letko، نويسنده , , Christopher S. and Cousineau، نويسنده , , Kandarpa D. and Hollis، نويسنده , , T. Keith، نويسنده ,
Abstract :
An air- and water-stable CCC–NHC pincer Rh complex catalyzed the 1,4-addition of aryl boronic acids to α,β-unsaturated ketones and aldehydes. This bench top method proceeds in eco-friendly solvents including methanol and water. The scope of boronic acids was expanded to include heterocyclic examples.
Keywords :
Michael reaction , CCC–NHC pincer ligand , Aryl boronic acids , Catalysis
