Title of article
The enormous apparent gas-phase acidity of cubylamine
Author/Authors
Abboud، نويسنده , , José-Luis M. and Alkorta، نويسنده , , Ibon and Burk، نويسنده , , Peeter and Dلvalos، نويسنده , , Juan Z. and Quintanilla، نويسنده , , Esther and Della، نويسنده , , Ernest W. and Koppel، نويسنده , , Ilmar A. and Koppel، نويسنده , , Ivar، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
560
To page
563
Abstract
The high acidity of cubylamine (1NH2) seems to originate in the release of strain energy attending the breaking of some C–C bonds in 1NH−. This process is greatly facilitated by the strong stereoelectronic interactions in 1NH−. The anionic species thus formed are less strained, and their corresponding conjugate acids seem unable to ‘borrow strength’ from the residual strain, at least within the time-scale of the FT ICR experiments.
Journal title
Chemical Physics Letters
Serial Year
2004
Journal title
Chemical Physics Letters
Record number
1913301
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