Author/Authors :
Abboud، نويسنده , , José-Luis M. and Alkorta، نويسنده , , Ibon and Burk، نويسنده , , Peeter and Dلvalos، نويسنده , , Juan Z. and Quintanilla، نويسنده , , Esther and Della، نويسنده , , Ernest W. and Koppel، نويسنده , , Ilmar A. and Koppel، نويسنده , , Ivar، نويسنده ,
Abstract :
The high acidity of cubylamine (1NH2) seems to originate in the release of strain energy attending the breaking of some C–C bonds in 1NH−. This process is greatly facilitated by the strong stereoelectronic interactions in 1NH−. The anionic species thus formed are less strained, and their corresponding conjugate acids seem unable to ‘borrow strength’ from the residual strain, at least within the time-scale of the FT ICR experiments.
