Author/Authors :
Lampre، نويسنده , , I. and Lin، نويسنده , , M. and He، نويسنده , , H. and Han، نويسنده , , Z. and Mostafavi، نويسنده , , M. and Katsumura، نويسنده , , Y.، نويسنده ,
Abstract :
Using nanosecond pulse radiolysis, the absorption spectra of the solvated electron have been recorded at different temperatures from 295 to 498 K in 1,2-propanediol (12PD) and 1,3-propanediol (13PD). In both solvents, the optical spectra shift to the red with increasing temperature. While the shape of the spectra does not change in 13PD, a widening on the blue side of the absorption band is observed in 12PD by increasing the temperature from 296 to 473 K.
