Author/Authors :
Drewello، نويسنده , , Thomas and Frauendorf، نويسنده , , Holm and Herzschuh، نويسنده , , Rainer and Goryunkov، نويسنده , , Alexey A. and Strauss، نويسنده , , Steven H. and Boltalina، نويسنده , , Olga V.، نويسنده ,
Abstract :
Isolated dianions of highly fluorinated [60]fullerenes have been produced for the first time with direct electrospray ionization (ESI). Stable dianions have been observed by spraying extremely dilute solutions of neutral fluorofullerenes, which may enhance their formation and/or prevent their depletion by the unwanted electron detachment. The formation of C 60 F x 2 - dianions provides a striking example of the electrochemical nature of the ESI process.
