Diameter control and growth mechanism of single-walled carbon nanotubes

Single-walled carbon nanotubes (SWNTs) have been synthesized using the alcohol chemical vapor deposition technique. On comparing the SWNTs synthesized using different catalyst compositions, an obvious fact has been clarified – the diameter of SWNTs is strongly dependent on the sizes of the catalyst particles and metal species. Iron atoms exhibit a strong interaction with carbon atoms and keep their diameters narrow. Cobalt atoms exhibit a poorer interaction than the iron atoms, but work to decompose ethanol. As a result, narrow SWNTs are generated on the iron-rich catalyst. In this Letter, we propose the most probable growth mechanism of the SWNTs.