Title of article :
Vibronic emission spectrum of the jet-cooled 2,6-dichlorobenzyl radical in a corona excited supersonic expansion
Author/Authors :
Lee، نويسنده , , Sang-kuk and Kim، نويسنده , , Seung Joo، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Pages :
4
From page :
88
To page :
91
Abstract :
The precursor 2,6-dichlorotoluene seeded in a large amount of carrier gas He was electrically discharged and expanded through a pinhole-type glass nozzle to generate the jet-cooled 2,6-dichlorobenzyl radical in a corona excited supersonic expansion. The visible emission spectrum of the jet-cooled 2,6-dichlorobenzyl radical in the D1 → D0 transition was recorded for the first time. The excited electronic energy and several vibrational mode frequencies in the ground electronic state were determined from the analysis of the spectrum by comparing with those of 2,6-dichlorotoluene as well as those from an ab initio calculation.
Journal title :
Chemical Physics Letters
Serial Year :
2005
Journal title :
Chemical Physics Letters
Record number :
1916136
Link To Document :
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