Author/Authors :
Zhang، نويسنده , , Yufeng and Wang، نويسنده , , Shancai and Learmonth، نويسنده , , Timothy and Plucinski، نويسنده , , Lukasz and Matsuura، نويسنده , , A.Y. and Bernardis، نويسنده , , Sarah and O’Donnell، نويسنده , , Cian and Downes، نويسنده , , James E. and Smith، نويسنده , , Kevin E.، نويسنده ,
Abstract :
The electronic structure of the organic semiconductor vanadium oxide phthalocyanine has been studied using resonant inelastic X-ray scattering and X-ray emission spectroscopy. The vanadyl species in the films is shown to be highly localized, and good agreement between the measurements and a density functional calculation is obtained. Both dipole forbidden V 3d to V 3d*, and O 2p to V 3d* charge transfer transitions are observed, and explained in a local molecular orbital model.
