Author/Authors :
Brandt، نويسنده , , Nikolai N. and Chikishev، نويسنده , , Andrey Yu. and Sakodinskaya، نويسنده , , Inna K. and Takahashi، نويسنده , , Hiroaki، نويسنده ,
Abstract :
A chain of photoinduced transformations of a photosensitively labeled crown ether (p-azido-benzo-18-crown-6) is studied in organic solvent and water to estimate the radiation dozes needed for optimum binding of photolabel. Transient absorption spectra of p-azido-benzo-18-crown-6 are measured with picosecond time resolution. The well-known photoinduced dynamics of phenylazide is compared to the dynamics of p-azido-benzo-18-crown-6.
