Exact matrix computation of the statistical mechanics of a cell model of hard sphere phase behaviour
Author/Authors :
Dunne، نويسنده , , Lawrence J. and Murrell، نويسنده , , John N. and Manos، نويسنده , , George and Rekabi، نويسنده , , Mahdi، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2006
Pages :
5
From page :
47
To page :
51
Abstract :
An exact calculation of the statistical mechanics of a cell model of hard-sphere isotherm behaviour is presented. Our calculation attributes the observed steps in the pressure–volume isotherms to entropic effects caused by the volume of space excluded by the hard core.