Author/Authors :
Guerra، نويسنده , , Doris and Castillo، نويسنده , , Raquel C. Andrés-Hyman، نويسنده , , J. and Fuentealba، نويسنده , , P. and Aizman، نويسنده , , A. and Contreras، نويسنده , , R.، نويسنده ,
Abstract :
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a series of SH2 processes involving organometallic systems.