Characterization of clusters produced by electronic sputtering

The structures and abundances of C n = 2 – 16 + clusters produced by electronic sputtering from the impact of 252Cf fission fragments on CO ice and from the UV laser desorption of amorphous carbon and graphite targets are analyzed. A systematic search for the more stable conformers at the DFT/B3LYP level of calculation and their contribution to the mass spectra is reported. A new methodology for a proper taxonomic description of the cluster isomers is proposed. Besides the known linear and monocyclic clusters series, new members of these series and two new series are described: the bi-cyclic and/or tri-cyclic and the rhombic core series.