Author/Authors :
Abo-Riziq، نويسنده , , Ali and Bushnell، نويسنده , , John E. and Crews، نويسنده , , Bridgit and Callahan، نويسنده , , Michael and Grace، نويسنده , , Louis and de Vries، نويسنده , , Mattanjah S. de Vries، نويسنده ,
Abstract :
IR–UV double resonance spectroscopy of the laser-desorbed, jet-cooled pentapeptide FDASV shows only one type of conformer in the gas phase. Comparison with computations at the B3LYP/6-31G∗∗ level suggests formation of an α-turn in the absence of solvent stabilization.