Author/Authors :
Amadei، نويسنده , , Andrea and D’Abramo، نويسنده , , Marco and Nola، نويسنده , , Alfredo Di and Arcadi، نويسنده , , Antonio and Cerichelli، نويسنده , , Giorgio and Aschi، نويسنده , , Massimiliano، نويسنده ,
Abstract :
In this Letter, we use the perturbed matrix method, in combination with molecular dynamics and statistical mechanics, in order to describe in details the electric field induced intramolecular charge transfer (ICT) in two π-conjugated oligomers of nanotechnological interest. Results show a relevant relationship between the extent of ICT and molecular conformation, pointing out the highly non-linear charge transfer field response.
