Author/Authors :
Chen، نويسنده , , Jie and Zhang، نويسنده , , Hua and Tomov، نويسنده , , Ivan V. and Ding، نويسنده , , Xunliang and Rentzepis، نويسنده , , Peter M.، نويسنده ,
Abstract :
By means of ultrafast optical transient spectroscopy and EXAFS we have measured the transient spectra kinetics and Fe–O bond length of the ferrioxalate redox reaction transients. Based on Fe–O bond distances of the photoredox intermediates and quantum chemistry DFT and H–F calculations we propose a photoredox mechanism where photodissociation precedes electron transfer.
