Author/Authors :
Feldman، نويسنده , , Vladimir I. and Sukhov، نويسنده , , Fedor F. and Logacheva، نويسنده , , Elizaveta A. and Orlov، نويسنده , , Aleksei Yu. and Tyulpina، نويسنده , , Irina V. and Tyurin، نويسنده , , Daniil A.، نويسنده ,
Abstract :
Chemical reactions induced by fast electron irradiation of benzene in solid xenon were studied by EPR and FTIR spectroscopy. Irradiation at 16 K leads to H atoms and phenyl radicals. Annealing at 45 K results in formation of HXeH and cyclohexadienyl radical (C6H7). A strong IR absorption at 618/620 cm−1 and several weaker bands were assigned to cyclohexadienyl radical from comparison with EPR data and DFT calculations. A computationally stable molecule HXeC6H5 was not found experimentally, which means that it is either not formed or not stabilized under the experimental conditions used.
