Author/Authors :
Zhang، نويسنده , , Xuan and Komoto، نويسنده , , Yusuke and Sakota، نويسنده , , Kenji and Nakagaki، نويسنده , , Masayuki and Nakano، نويسنده , , Haruyuki and Shinmyozu، نويسنده , , Teruo and Sekiya، نويسنده , , Hiroshi، نويسنده ,
Abstract :
The measurement of the electronic spectra of jet-cooled 4-chloro-7-azaindole dimer (4CAI2) revealed that the Cl substitution substantially suppresses the excited-state double-proton transfer (ESDPT). Quantum chemistry calculation at the CIS level suggested that the change in the intermolecular stretching mode, which promotes ESDPT, is important for the suppression of ESDPT.
