Author/Authors :
Lünnemann، نويسنده , , Siegfried and Kuleff، نويسنده , , Alexander I. and Cederbaum، نويسنده , , Lorenz S. Cederbaum، نويسنده ,
Abstract :
Electron correlation can be the driving force for ultrafast charge migration. Using ab initio calculations this is demonstrated in the present paper for the first time as a consequence of ionizing the outer-valence shell. The example studied is 2-phenylethyl-N,N-dimethylamine (PENNA) on which exciting pump–probe measurements have been recently carried out.
