Title of article
Induced solvent chirality: A VCD study of camphor in CDCl3
Author/Authors
Debie، نويسنده , , Elke and Jaspers، نويسنده , , Lize and Bultinck، نويسنده , , Patrick and Herrebout، نويسنده , , Wouter and Veken، نويسنده , , Benjamin Van Der، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
5
From page
426
To page
430
Abstract
It is shown how the presence of a chiral compound in solution induces chirality in the surrounding solvent molecules. Using Vibrational Circular Dichroism on camphor dissolved in deuterated chloroform, it is found that the C–D stretch in the latter indeed becomes VCD active. The experimental results agree with ab initio computed spectra for 1:1 associations between the solvent and solute.
Journal title
Chemical Physics Letters
Serial Year
2008
Journal title
Chemical Physics Letters
Record number
1923318
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