Author/Authors :
Teramura، نويسنده , , Kentaro and Hosokawa، نويسنده , , Tomohiro and Ohuchi، نويسنده , , Tai and Shishido، نويسنده , , Tetsuya S. Tanaka، نويسنده , , Tsunehiro، نويسنده ,
Abstract :
The photoluminescence spectrum and action spectrum for the photooxidation of orthovanadate-like (V=O)O3 species exhibiting photoluminescence at 520 nm indicate that the triplet excited state T1 of the orthovanadate-like species, which is formed from the singlet excited states S1 and S2 by intersystem crossing, is directly involved in the photooxidation of cyclohexane into cyclohexanone in the presence of molecular oxygen.
