Author/Authors :
Giuliano، نويسنده , , Barbara M. and Castrovilli، نويسنده , , Mattea C. and Maris، نويسنده , , Assimo and Melandri، نويسنده , , Sonia and Caminati، نويسنده , , Walther and Cohen، نويسنده , , Edward A.، نويسنده ,
Abstract :
The rotational spectra of tert-butanol···14NH3 and tert-butanol···15NH3 have been investigated and assigned by pulsed jet Fourier transform microwave spectroscopy. According to the values of the 14N quadrupole coupling constants, the complex (where NH3 acts as a proton acceptor) adopts a configuration with an almost linear O–H···N hydrogen bond. The NH3 moiety undergoes a nearly free rotation.
