Author/Authors :
Orimi، نويسنده , , Kenichi and Watanabe، نويسنده , , Shinji and Kohguchi، نويسنده , , Hiroshi and Yamasaki، نويسنده , , Katsuyoshi، نويسنده ,
Abstract :
A gaseous mixture of O3/OCS/He was irradiated at 266 nm with a pulsed laser, and vibrationally excited SO(X3Σ−, v = 8 and 19) generated in the reaction of O(1D) with OCS was detected with the laser-induced fluorescence (LIF) via the B3Σ− – X3Σ− system. The apparent production rates of SO(v = 8) in the initial reaction time and their OCS pressure dependence have been measured, giving the absolute overall rate coefficient for the O(1D) + OCS reaction.