Author/Authors :
Deng، نويسنده , , Changmin and Gong، نويسنده , , Pei and He، نويسنده , , Qingguo and Cheng، نويسنده , , Jiangong and He، نويسنده , , Chao and Shi، نويسنده , , Liqi and Zhu، نويسنده , , Defeng and Lin، نويسنده , , Tong، نويسنده ,
Abstract :
Well-aligned nanofibers were prepared from a conjugated polymer, poly(triphenylamine-alt-biphenylene vinylene) (TPA-PBPV), using a solution-assisted template wetting technique. TPA-PBPV was also coated on the surface of electrospun polyacrylonitrile (PAN) nanofiber nonwoven membrane. The extremely large surface area, highly porous fibrous structure, optical scattering and evanescent-wave guiding effect imparted these one-dimensional (1D) nanofibrous materials with highly improved sensory ability to 2,4,6-trinitrotoluene (TNT) vapors and higher quenching efficiency than that of the neat TPA-PBPV films. The results suggest that nanofibrous structures could be a promising strategy to improve the sensory efficiency of fluorescent chemosensors.