Author/Authors :
Nilsson، نويسنده , , Elna J.K. and Hoff، نويسنده , , Janus and Nielsen، نويسنده , , Ole John and Johnson، نويسنده , , Matthew S.، نويسنده ,
Abstract :
The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220–330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10−12 exp((−1011 ± 24)/T) cm3 molecule−1 s−1.
