Title of article
Can two trivalent N atoms engage in a direct N⋯N noncovalent interaction?
Author/Authors
Scheiner، نويسنده , , Steve، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
32
To page
35
Abstract
While the two N atoms of a pair of NH3 molecules do not interact attractively, the replacement of one H with a F atom results in a direct N⋯N noncovalent bond, with an interaction energy of 4 kcal/mol, nearly as strong as a NH⋯N H-bond. Cl or Br-substitution also leads to an attractive force between the two N atoms, although the XN⋯N geometry does not represent a true minimum on the potential energy surface. Trimethylation of the electron donor NH3 strengthens both the NH⋯N and XN⋯N bonds.
Journal title
Chemical Physics Letters
Serial Year
2011
Journal title
Chemical Physics Letters
Record number
1931956
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