• Title of article

    Can two trivalent N atoms engage in a direct N⋯N noncovalent interaction?

  • Author/Authors

    Scheiner، نويسنده , , Steve، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2011
  • Pages
    4
  • From page
    32
  • To page
    35
  • Abstract
    While the two N atoms of a pair of NH3 molecules do not interact attractively, the replacement of one H with a F atom results in a direct N⋯N noncovalent bond, with an interaction energy of 4 kcal/mol, nearly as strong as a NH⋯N H-bond. Cl or Br-substitution also leads to an attractive force between the two N atoms, although the XN⋯N geometry does not represent a true minimum on the potential energy surface. Trimethylation of the electron donor NH3 strengthens both the NH⋯N and XN⋯N bonds.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    2011
  • Journal title
    Chemical Physics Letters
  • Record number

    1931956