Title of article :
Can two trivalent N atoms engage in a direct N⋯N noncovalent interaction?
Author/Authors :
Scheiner، نويسنده , , Steve، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Pages :
4
From page :
32
To page :
35
Abstract :
While the two N atoms of a pair of NH3 molecules do not interact attractively, the replacement of one H with a F atom results in a direct N⋯N noncovalent bond, with an interaction energy of 4 kcal/mol, nearly as strong as a NH⋯N H-bond. Cl or Br-substitution also leads to an attractive force between the two N atoms, although the XN⋯N geometry does not represent a true minimum on the potential energy surface. Trimethylation of the electron donor NH3 strengthens both the NH⋯N and XN⋯N bonds.
Journal title :
Chemical Physics Letters
Serial Year :
2011
Journal title :
Chemical Physics Letters
Record number :
1931956
Link To Document :
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