Author/Authors :
Bowman، نويسنده , , R.M. and Dantus، نويسنده , , M. and Zewail، نويسنده , , A.H.، نويسنده ,
Abstract :
The application of femtosecond transition-state spectroscopy (FTS) to molecular iodine is reported. The real-time motion of wave packets prepared coherently in the bound B state is observed. In addition, the motion is probed near and above the dissociation limit for the reaction: I2 → I (2P3/2) + I∗(2P1/2). FTS measurements of the dynamics on repulsive surfaces are also reported.