Author/Authors :
Bogdanov، نويسنده , , Andrei V. and Pashirova، نويسنده , , Tatiana N. and Musin، نويسنده , , Lenar I. and Krivolapov، نويسنده , , Dmitry B. and Zakharova، نويسنده , , Lucia Ya. and Mironov، نويسنده , , Vladimir F. and Konovalov، نويسنده , , Alexander I.، نويسنده ,
Abstract :
A mild, catalyst-free and simple synthesis of 1,1′-di(n-alkyl)-isoindigo via the reaction of substituted isatins with tris(diethylamino)phosphine is reported. Their self-assembly in water–DMF (50% v/v) solution was investigated. Unexpectedly, no surface activity was observed for compound 2h. Spectrophotometry and fluorimetry allowed determining critical micelle concentration (0.1 mM and 0.8 mM respectively). Aggregation numbers of 8 and sizes of aggregates were determined.
