Author/Authors :
Jalife، نويسنده , , Abril Carolina and Audiffred، نويسنده , , Martha and Islas، نويسنده , , Rafael and Escalante، نويسنده , , Sigfrido and Pan، نويسنده , , Sudip and Chattaraj، نويسنده , , Pratim K. and Merino، نويسنده , , Gabriel، نويسنده ,
Abstract :
Inspired by carbo-benzene, we have analyzed in silico the stability of carbo-borazine (C12B3N3H6) and the iminobora-mer of borazine (B9N9H6). Both systems may be regarded as the inorganic analogues of carbo-benzene, being B9N9H6 the perfect case. Unlike aromatic carbo-benzene, C12B3N3H6 and B9N9H6 can be classified as almost nonaromatic systems as indicated by the computed induced magnetic field. All these systems undergo dimerization very readily; therefore, they cannot be synthesized as such. However, akin to substituted carbo-benzene, the substitution of the hydrogen atom of C12B3N3H6 and B9N9H6 by other groups could stabilize them.
