Title of article
Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2COClCH3
Author/Authors
Tanaka، نويسنده , , Nobuaki and Urashima، نويسنده , , Yoshitaka and Nishikiori، نويسنده , , Hiromasa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
5
From page
258
To page
262
Abstract
The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2CO and a cyclopropanone⋯HCl complex. The cyclopropanone⋯HCl complex was further decomposed into CH2CH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane.
Journal title
Chemical Physics Letters
Serial Year
2014
Journal title
Chemical Physics Letters
Record number
1937577
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