• Title of article

    The synthesis of NH4Zr2F9 and its conversion to ZrO2

  • Author/Authors

    Lin، نويسنده , , Feng-Qiang and Dong، نويسنده , , Wensheng and Liu، نويسنده , , Chun-Ling and Li، نويسنده , , Men-Yuan، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2009
  • Pages
    7
  • From page
    1
  • To page
    7
  • Abstract
    Rosette-like ammonium flurorzirconate (NH4Zr2F9) aggregates have been synthesized via a novel reaction route by using zirconium oxychloride, urea, 1-butyl-3-methylimidazolium tetrafluoroborate (BMImBF4) and hydrochloric acid in ethanol solution. The as-synthesized NH4Zr2F9 can be changed from rosette-like aggregates to hexagonal plates by varying synthesis conditions. Upon calcination at high temperature NH4Zr2F9 transforms from relative dense structure into highly porous ZrO2 with similar morphology consisting of interconnected nanocrystallites.
  • Keywords
    Ammonium flurorzirconate , Zirconia , Ionic liquids
  • Journal title
    Colloids and Surfaces A Physicochemical and Engineering Aspects
  • Serial Year
    2009
  • Journal title
    Colloids and Surfaces A Physicochemical and Engineering Aspects
  • Record number

    1937771