Title of article
Reactions of bis[bis(trimethylsilyl)amido] zinc with amides of sulfonimidic acids. Crystal structure and NMR studies of bischelate zinc complex
Author/Authors
Guzyr، نويسنده , , Olexandr I. and Markovskii، نويسنده , , Leonid N. and Povolotskii، نويسنده , , Mark I. and Roesky، نويسنده , , Herbert W. and Chernega، نويسنده , , Alexander N. and Rusanov، نويسنده , , Eduard B.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
89
To page
92
Abstract
Reactions of bis[bis(trimethylsilyl)amido] zinc with amides of sulfonimidic acids are leading to the corresponding bischelate complexes 1–3. Compounds 1–3 were characterized by means of NMR spectroscopy and elemental analysis. The X-ray analysis of [p-MeC6H4S(O)(Nt-Bu)2]2Zn (3) demonstrates a tetrahedral environment of the Zn atom in the solid state and dynamic 1H NMR studies showed interconvention between two conformers in solution at high temperatures.
Keywords
complexes , Zinc , Sulfur , Solid-state structures , N ligands
Journal title
Journal of Molecular Structure
Serial Year
2006
Journal title
Journal of Molecular Structure
Record number
1962807
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