Title of article
1H, 13C and 15N NMR, FT-IR as well as PM5 studies of a new Schiff base of gossypol with 3,6-dioxadecylamine in solution
Author/Authors
Przybylski، نويسنده , , Piotr and Lewandowska، نويسنده , , Weronika and Brzezinski، نويسنده , , Bogumil and Bartl، نويسنده , , Franz، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
7
From page
92
To page
98
Abstract
The Schiff base of racemic gossypol with 3,6-dioxadecylamine (GSDN) has been synthesised and its structure has been studied by FT-IR, 1H, 13C and 15N NMR spectroscopy as well as by the PM5 semiempirical method. All spectroscopic methods have provided respective evidences that GSDN in solution exists exclusively in the enamine–enamine tautomeric form. The structure of the enamine–enamine tautomer is visualized and the hydrogen bonds stabilising this structure are discussed.
Keywords
Hydrogen bonds , gossypol , Schiff base , 3 , 6-Dioxadecylamine , 15N NMR , 13C NMR , 1H NMR , COSY , HETCOR , FT-IR , PM5 , tautomers
Journal title
Journal of Molecular Structure
Serial Year
2006
Journal title
Journal of Molecular Structure
Record number
1963279
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