Title of article
Bromodifluoroacetyl fluoride, CF2BrC(O)F: Experimental and theoretical studies
Author/Authors
Arce، نويسنده , , Valeria B. and Czarnowski، نويسنده , , Joanna and Romano، نويسنده , , Rosana M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
32
To page
37
Abstract
Bromodifluoroacetyl fluoride, CF2BrC(O)F, was prepared through the gas-phase reaction of bromotrifluoroethene, CF2CFBr, with molecular oxygen initiated either by NO2 or CF3OF. The compound was experimentally studied by FTIR spectroscopy of the gas phase and also isolated in Ar and N2 matrices at low temperature. The energy differences between the possible conformers were theoretically studied, as well as the vibrational spectra of the conformers.
Keywords
Matrix isolation , Gas-phase reaction , conformational analysis , Bromodifluoroacetyl fluoride , Theoretical calculations , FTIR SPECTROSCOPY
Journal title
Journal of Molecular Structure
Serial Year
2006
Journal title
Journal of Molecular Structure
Record number
1963446
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