Title of article :
Unexpected phase-jumps upon cycling around a conical intersection
Author/Authors :
Englman، نويسنده , , R. and Yahalom، نويسنده , , A. and Vértesi، نويسنده , , T.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
A non-mathematical formulation is given of possible multiple (not just ±π) geometric phase-jumps around conical intersections. It is based on variable cycling speed along the nuclear trajectory and on a rigorous handling of the adiabatic limit. Extremely high value π jumps occur even for a single conical intersection, if the trajectory starts near the degeneracy point.
Keywords :
molecules , Adiabatic motion , Berry phase
Journal title :
Journal of Molecular Structure
Journal title :
Journal of Molecular Structure