• Title of article

    Unexpected phase-jumps upon cycling around a conical intersection

  • Author/Authors

    Englman، نويسنده , , R. and Yahalom، نويسنده , , A. and Vértesi، نويسنده , , T.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2007
  • Pages
    4
  • From page
    20
  • To page
    23
  • Abstract
    A non-mathematical formulation is given of possible multiple (not just ±π) geometric phase-jumps around conical intersections. It is based on variable cycling speed along the nuclear trajectory and on a rigorous handling of the adiabatic limit. Extremely high value π jumps occur even for a single conical intersection, if the trajectory starts near the degeneracy point.
  • Keywords
    molecules , Adiabatic motion , Berry phase
  • Journal title
    Journal of Molecular Structure
  • Serial Year
    2007
  • Journal title
    Journal of Molecular Structure
  • Record number

    1963968