Title of article
Unexpected phase-jumps upon cycling around a conical intersection
Author/Authors
Englman، نويسنده , , R. and Yahalom، نويسنده , , A. and Vértesi، نويسنده , , T.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
20
To page
23
Abstract
A non-mathematical formulation is given of possible multiple (not just ±π) geometric phase-jumps around conical intersections. It is based on variable cycling speed along the nuclear trajectory and on a rigorous handling of the adiabatic limit. Extremely high value π jumps occur even for a single conical intersection, if the trajectory starts near the degeneracy point.
Keywords
molecules , Adiabatic motion , Berry phase
Journal title
Journal of Molecular Structure
Serial Year
2007
Journal title
Journal of Molecular Structure
Record number
1963968
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