Author/Authors :
Yi، نويسنده , , Zhi-hui and Cui، نويسنده , , Xiao-Bing and Zhang، نويسنده , , Xiao and Xu، نويسنده , , Jiqing and Yang، نويسنده , , Guang-Di and Chen، نويسنده , , Yan and Wang، نويسنده , , Tiegang and Yu، نويسنده , , Xiao-Yang، نويسنده ,
Abstract :
A novel polyoxometalate {[Ni(enMe)2]2[Ni(enMe)2(H2O)]2[As2W18Ni4(enMe)2O68]}·2H3O·2H2O (1) (enMe = 1,2-propylenediamine) has been synthesized and characterized, which is the first high-dimensional structure constructed from sandwich-type transition metal substituted tungstates and transition metal coordination groups.
Keywords :
Polyoxometalate , hydrothermal synthesis , Sandwich-type cluster , crystal structure
