Title of article
Metallosupramolecular zinc and cadmium complexes of Bis[4-(2-pyridyl)pyrimidinylthiomethyl]benzenes
Author/Authors
Dong، نويسنده , , Huaze and Zhu، نويسنده , , Haibin and Tong، نويسنده , , Taifeng and Gou، نويسنده , , Shaohua، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
6
From page
266
To page
271
Abstract
Reactions of L1 and L2 (L1 = 1,4-bis[4-(2-pyridyl)pyrimidinylthiomethyl] benzene; L2 = 1,3-bis[4-(2-pyridyl)pyrimidinylthiomethyl]benzene) with CdI2, ZnI2 and Cd(NO3)2 led to the formation of two discrete bimetallic complexes and one single-handed helix, respectively. Conformation changes of ligands after interactions with metal salts were found due to the positional isomerism of xylyl groups and the effect of anions.
Keywords
Dinuclear complexes , Single-handed helix , Metallosupramolecule , Structure elucidation
Journal title
Journal of Molecular Structure
Serial Year
2008
Journal title
Journal of Molecular Structure
Record number
1965629
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