Title of article
Synthesis and theoretical study of bis(fluoroisatinato) mercury(II)
Author/Authors
Kandemirli، نويسنده , , Fatma and K?ksoy، نويسنده , , Baybars and Arslan، نويسنده , , Taner and Sagd?nc، نويسنده , , Seda and Berber، نويسنده , , Halil، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
6
From page
172
To page
177
Abstract
Bis(fluoroisatinato)mercury(II) was synthesised from the reaction between 5-fluoroisatin (HFI) and mercury(II) acetate in methanol. Mercury(II) coordination with nitrogen atom of 5-fluoroisatin molecule was observed using the FT-IR and NMR spectra of the product. Quantum chemistry calculations for 5-fluoroisatin (HFI) and bis(fluoroisatinato)mercury(II) (Hg(FI)2) were carried out. Vibrational analysis calculation at the RHF/LanL2DZ and B3LYP/LanL2DZ level was compared to the experimental solid-state data. UV-visible analyses were also studied.
Keywords
UV , Bis(fluoroisatinato)mercury(II) , 5-Fluoroisatin , FT-IR , Quantum-chemical calculation
Journal title
Journal of Molecular Structure
Serial Year
2009
Journal title
Journal of Molecular Structure
Record number
1966246
Link To Document