Title of article
High thermal stability and antiferromagnetic properties of a 3D Mn(II)-organic framework with metal carboxylate chains
Author/Authors
Han، نويسنده , , Lei and Zhou، نويسنده , , Yan and Wang، نويسنده , , Xiu-Teng and Li، نويسنده , , De-Xing and Tong، نويسنده , , Ming-Liang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
24
To page
27
Abstract
A novel three-dimensional metal-organic framework, [Mn2(hfipbb)2(bpy)]n (1) (H2hfipbb = 4,4′-(hexafluoroisopropylidene)bis(benzoic acid), bpy = 4,4′-bipyridine), has been hydrothermally synthesized and structurally characterized. The complex consists of metal carboxylate chains, which are cross-linked to six adjacent chains through organic moieties forming extended three-dimensional networks. Complex 1 exhibits high thermal stability (450 °C) and antiferromagnetic properties.
Keywords
Metal carboxylate chain , antiferromagnetic , thermal stability , metal-organic framework
Journal title
Journal of Molecular Structure
Serial Year
2009
Journal title
Journal of Molecular Structure
Record number
1966345
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