Title of article :
Synthesis and crystal molecular structure of ferracarborane commo-(3-Fe-{1,2-C2B9H9-4-SMe2-12-HgCl}2)
Author/Authors :
Starikova، نويسنده , , Z.A. and Lobanova، نويسنده , , I.A. and Timofeev، نويسنده , , S.V. and Bregadze، نويسنده , , V.I.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Symmetrically substituted dimercuro-ferracarborane commo-(3-Fe-{1,2-C2B9H9-4-SMe2-12-HgCl}2) (1) was synthesized and its structure was determined by single crystal X-ray diffraction. The molecule adopts a staggered sandwich structure with the dicarbollide ligands forming cisoid conformation. Strong intermolecular interactions Hg…C1 and S…Cl lead to formation of 1D chains {commo-(3-Fe-{1,2-C2B9H9-4-SMe2-12-HgCl}2)}∞.
Keywords :
Charge-compensated ferracarboranes , single crystal X-ray diffraction , Mercuration
Journal title :
Journal of Molecular Structure
Journal title :
Journal of Molecular Structure
