Author/Authors :
Pintos، نويسنده , , V. and Cuevas، نويسنده , , A. and Onetto، نويسنده , , S. and Seoane، نويسنده , , G. and Denis، نويسنده , , P.A. and Gancheff، نويسنده , , J.S. and Faccio، نويسنده , , R. and Mombrْ، نويسنده , , A.W. and Kremer، نويسنده , , C.، نويسنده ,
Abstract :
The azine bridged dicatechol ligand (E,E)-benzaldehyde azine (H4L) was fully characterized by X-ray analysis. The reaction of [ReCl6]2− with this compound was studied and the novel Re(IV) complex (HNEt3)(NBu4)[ReCl4(H2L)] was prepared and characterized. The structure and spectroscopy of the compound H4L and its Re(IV) complex were studied experimentally and by means of density functional calculations.
Keywords :
Dicatechol , Rhenium(IV) , X-ray structure , DFT calculations
