• Title of article

    Structural and theoretical studies of (E,E)-benzaldehyde azine and its rhenium(IV) complex

  • Author/Authors

    Pintos، نويسنده , , V. and Cuevas، نويسنده , , A. and Onetto، نويسنده , , S. and Seoane، نويسنده , , G. and Denis، نويسنده , , P.A. and Gancheff، نويسنده , , J.S. and Faccio، نويسنده , , R. and Mombrْ، نويسنده , , A.W. and Kremer، نويسنده , , C.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2010
  • Pages
    7
  • From page
    9
  • To page
    15
  • Abstract
    The azine bridged dicatechol ligand (E,E)-benzaldehyde azine (H4L) was fully characterized by X-ray analysis. The reaction of [ReCl6]2− with this compound was studied and the novel Re(IV) complex (HNEt3)(NBu4)[ReCl4(H2L)] was prepared and characterized. The structure and spectroscopy of the compound H4L and its Re(IV) complex were studied experimentally and by means of density functional calculations.
  • Keywords
    Dicatechol , Rhenium(IV) , X-ray structure , DFT calculations
  • Journal title
    Journal of Molecular Structure
  • Serial Year
    2010
  • Journal title
    Journal of Molecular Structure
  • Record number

    1967030