Title of article
Solvothermal synthesis, crystal structure and magnetic behavior of a Schiff base heterometallic cluster
Author/Authors
Chen، نويسنده , , Fa-Yun and Zhang، نويسنده , , Shu Hua and Li، نويسنده , , He Ping and Zhang، نويسنده , , Lai Jun and Zhang، نويسنده , , Yi Dong، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
5
From page
142
To page
146
Abstract
The reaction of Ni(ClO4)2·6H2O with a dilithium 2-[(2-hydroxy-3-ethoxy-enzylidene)-amino]-ethane sulfonic acid (Li2L) in a acetonitrile solution under solvothermal conditions leads to the formation of heterometallic tetranuclear cubane cluster [Ni3Li(L)3(OH)(CH3CN)3]·0.5CH3CN (1, where Li2L = dilithium 2-[(2-hydroxy-3-ethoxy-benzylidene)-amino]-ethanesulfonate). Complex 1 displays dominant ferromagnetic interactions through μ3-O (oxidophenyl and hydroxyl) binding modes.
Keywords
Magnetic properties , Heterometallic cubane cluster , N , O ligand
Journal title
Journal of Molecular Structure
Serial Year
2011
Journal title
Journal of Molecular Structure
Record number
1969240
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