Title of article
Special hydrogen bonds observed in two monovalent metal carboxylate–phosphinates: {NaH(PhPO2C2H4COOH)2}∞ and {[KH(PhPO2C2H4COOH)2]·H2O}∞
Author/Authors
Zhao، نويسنده , , Cui-Cui and Zhang، نويسنده , , Jianwei and Zhou، نويسنده , , Zhong-Gao and Du، نويسنده , , Zi-Yi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
253
To page
257
Abstract
The addition of strong base such as sodium hydroxide or potassium hydroxide to the aqueous solution of (2-carboxyethyl)(phenyl)phosphinic acid afforded two novel monovalent metal carboxylate–phosphinates, namely, {NaH(PhPO2C2H4COOH)2}∞ (1) and {[KH(PhPO2C2H4COOH)2]·H2O}∞ (2). They represent the first examples of phosphinate containing short, symmetric or almost symmetric O⋯H⋯O hydrogen bonds.
Keywords
Hydrogen bond , Phosphinate , sodium , potassium , crystal structure
Journal title
Journal of Molecular Structure
Serial Year
2013
Journal title
Journal of Molecular Structure
Record number
1972726
Link To Document