Title of article :
Studies towards rotational dynamics of dimethyl 2-(triphenylphosphoranylidene) succinate by 1H NMR
Author/Authors :
Rodrigues، نويسنده , , Shirley M.M. and Palaretti، نويسنده , , Vinicius and Nardini، نويسنده , , Viviani and Constantino، نويسنده , , Mauricio G. and da Silva، نويسنده , , Gil Valdo J.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
We describe here the dynamic 1H NMR studies of dimethyl 2-(triphenylphosphoranylidene) succinate (1). Phosphorane 1 has a bond presenting slow (in the 1H NMR time scale) rotation which results in spectra of two isomers at the same time. From the spectral data were calculated the rate constant and thermodynamic parameters for the rotational process.
Keywords :
Gibbs free energy of activation , Geometrical isomers , Dynamic 1H NMR , solvent effects
Journal title :
Journal of Molecular Structure
Journal title :
Journal of Molecular Structure
