Preparation, spectral investigation and spectrophotometric studies of proton transfer complex of 2,2′-bipyridine with 3,5-dinitrobenzoic acid in various polar solvents

The charge transfer interactions between 2,2′-bipyridine and 3,5-dinitrobenzoic acid result in an interesting new charge transfer (CT) complex compound. During spectrophotometric study absorption maxima found at 235 nm, 236 nm, 240 nm and 275 nm in ethanol, methanol, acetonitrile, DMF respectively, show solvent effect in various aspects. Spectrophotometry and FTIR spectroscopy were used to define the properties of the complex formed. Spectrophotometric data explained the properties of complex in terms of formation constant (KCT), molar extinction coefficient (εCT), energy of interaction (ECT), ionization potential (ID), resonance energy (RN), free energy (ΔG), oscillator strength (f) and transition dipole moment (μEN). Thermograms study was performed to give enthalpy and weight loss in various steps with temperature. The stoichiometry of CT complex was found to be 1:1 in solution state and however, it was 1:2 in solid state. CT complex was formed by proton transfer (CT) from DNBA to Byp showing O−⋯HN+ bonding. The agreements between the spectroscopic results were confirmed by single crystal X-ray of the resulting charge transfer complex.