Title of article :
Solid-liquid equilibria for systems containing long-chain 1-alkanols I. Experimental data for 1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol or 1-icosanolbenzene or toluene mixtures. Characterization in terms of DISQUAC
Author/Authors :
Doma?ska، نويسنده , , U. and Gonz?lez، نويسنده , , J.A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1996
Abstract :
Solid-liquid equilibrium temperatures for binary mixtures of long-chain 1-alkanols (1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol and 1-icosanol) and benzene or toluene have been measured by a dynamic method between 276 K and the melting point of the alcohol. These data are used, taking into consideration the two solid-solid first-order transitions observed in the 1-alkanols, to characterize in terms of DISQUAC the hydroxyl-aromatic interactions present in the investigated mixtures. The relative standard deviations for the equilibrium temperatures are less than 0.01 for most of the systems.
Keywords :
Solid-liquid equilibria , 1-alkanols , Experimental , transitions , group contributions
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria