Henryʹs constants of n-alkanols (methanol through n-hexanol) in water at temperatures between 40°C and 90°C

Henryʹs constants of n-alkanols (methanol to n-hexanol) in water were measured at temperatures between 40°C and 90°C using a recently developed headspace gas chromatographic technique. The data were in good agreement with literature data when available. The consistency of the data was verified by comparing calculated partial molar enthalpies with calorimetric values. The temperature dependence of dimensionless Henryʹs constants was fitted with the classical vanʹt Hoff equation and an empirical correlation was established for the dimensionless Henryʹs constants as a function of temperature and number of carbon atoms in the n-alkanol.