Title of article
Measurement and correlation of the solubility of MnSO4·H2O in ethanol + water + MgSO4·7H2O solutions
Author/Authors
Safaeefar، نويسنده , , P. O. Ang، نويسنده , , H.M. and Kuramochi، نويسنده , , H. and Asakuma، نويسنده , , Y. and Maeda، نويسنده , , K. and Tade، نويسنده , , M.O. and Fukui، نويسنده , , K.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
64
To page
69
Abstract
Data on the solubility of manganese sulphate monohydrate in water, and in aqueous alcohols is essential for salting-out crystallisation studies. The solubilities of the quaternary system MnSO4·H2O + MgSO4·7H2O + H2O + EtOH were determined in the temperature range 293.2–323.2 K over the ethanol mole fraction range of 0.00–0.12. The solubility data were used for modelling with the modified extended electrolyte non-random two-liquid (NRTL) equation. The present extension uses ion-specific parameters instead of the electrolyte-specific NRTL binary interaction parameters. This approach has feasibility for many electrolytes and mixed aqueous solution systems in principle. The model was found to correlate the solubility data satisfactorily.
Keywords
Multi-electrolytes , NRTL equations , Mixed solvent , Solubility of electrolytes , Manganese sulphate monohydrate
Journal title
Fluid Phase Equilibria
Serial Year
2006
Journal title
Fluid Phase Equilibria
Record number
1986225
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