Measurement and prediction of tie-line data for mixtures of (water + 1-propanol + diisopropyl ether): LLE diagrams as a function of temperature

Tie-line data for ternary system of (water + 1-propanol + diisopropyl ether (DIPE)) were determined at T = (298.2, 308.2 and 313.2) K under atmospheric conditions. The ternary system exhibited type-I LLE behavior, as (DIPE + water) is the only liquid pair that is partially miscible. The experimental data for this system were predicted with the UNIFAC model with a root mean square deviation of 2.64%. The reliability of the experimental tie-line data was determined through the Othmer–Tobias and Hand plots. Distribution coefficients and separation factors were measured to evaluate the extracting capability of the solvents. The influence of temperature effect on the equilibrium characteristics and separation factor was found to be significant at the temperatures studied.