• Title of article

    Determination and correlation of solubilities of 1,2-bis (2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane in selected solvents

  • Author/Authors

    Qi ، نويسنده , , Chunmei and Wang، نويسنده , , Li-Sheng and Du، نويسنده , , Jun-Chao and Yu، نويسنده , , Guomin and Sun، نويسنده , , Gui-Qin، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2013
  • Pages
    8
  • From page
    343
  • To page
    350
  • Abstract
    1,2-Bis (2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino) ethane (BPEA) was prepared, and characterized by elemental analysis (EA), mass spectra (MS), infrared spectroscopy (IR) and nuclear magnetic resonance (NMR). The melting point and the enthalpy of fusion of BPEA were performed on differential scanning calorimetry (DSC), and the thermal stability of BPEA was tested by thermogravimetric analysis (TGA). The solubility of BPEA in selected solvents was measured by a static analytical method. The experimental data were correlated with different thermodynamic models, such as the empirical equation and non-random two liquid (NRTL), Wilson, Scatchard–Hildebrand, and universal quasi chemical (UNIQUAC) equations. The calculated results showed good agreement with the experimental data in the temperature range studied.
  • Keywords
    solubility , Phosphorus–nitrogen compounds , Organic solvents , flame retardant
  • Journal title
    Fluid Phase Equilibria
  • Serial Year
    2013
  • Journal title
    Fluid Phase Equilibria
  • Record number

    1989750