Title of article :
(p, VE, T) Measurements of mixtures (DBE + alcohol) at temperatures from (293.15 to 353.15) K and at pressures up to 140 MPa
Author/Authors :
Alaoui، نويسنده , , Fatima E.M. and Montero، نويسنده , , Eduardo A. and Bazile، نويسنده , , Jean-Patrick and Aguilar، نويسنده , , Fernando and Boned، نويسنده , , Christian، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
This work reports new experimental density data (960 points) for 1-propanol and for binary mixtures of dibutyl ether + 1-propanol, +2-propanol and +1-hexanol over the full composition range (5 compositions; 0.15 ≤ dibutyl ether mole fraction x ≤ 0.85), between 293.15 and 353.15 K (every 20 K), and for 15 pressures from 0.1 MPa up to 140 MPa (every 10 MPa).
on Paar vibrating tube densimeter, calibrated with an uncertainty of ±0.5 kg m−3 was used to perform these measurements. The experimental density data were fitted with a Tait-like equation with low standard deviations. Excess volumes have been calculated from the experimental data and fitted by the Redlich–Kister equation. In addition, the isobaric thermal expansivity and the isothermal compressibility have been derived from the Tait-like equation.
Keywords :
Density , high pressure , Excess volume , dibutyl ether , alcohol
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria