Title of article :
Liquid–liquid equilibria of ionic liquid 1-(2-methoxyethyl)-3-methylimidazolium bromide + potassium carbonate, potassium phosphate, dipotassium phosphate + water aqueous two-phase systems
Author/Authors :
Sheng، نويسنده , , Chengzhuo and Han، نويسنده , , Juan and Wang، نويسنده , , Yun and Chen، نويسنده , , Bo and Liu، نويسنده , , Yu and Zhang، نويسنده , , Guocai and Yan، نويسنده , , Yongsheng and Zhao، نويسنده , , Xiaohong، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
Binodal curves of 1-(2-methoxyethyl)-3-methylimidazolium bromide + potassium carbonate, potassium phosphate, dipotassium phosphate + water aqueous two-phase systems were determined experimentally at T = 288.15, 298.15 and 308.15 K, respectively. Effect of temperature on binodal curves was studied. Two empirical equations were used for reproducing the experimental binodal data. Effective excluded volume (EEV) theory was used to investigate the phase-forming strength of salts PO43−>HPO42−>CO32−. Additionally, the tie-line data were correlated by the Othmer-Tobias, Bancroft and Setschenow-type equations.
Keywords :
Aqueous two-phase systems , Binodal curves , Liquid–liquid equilibria , Ionic liquid , Ether-functionalized
Journal title :
Fluid Phase Equilibria
Journal title :
Fluid Phase Equilibria